THE SHALLOW AND DEEP WELL WATERS OF ESSEX. 35 The East Donyland water contains about fifteen grains of carbonate of soda per gallon, the Colchester water No. I. about six grains, and No. II. none, the whole alkalinity being accounted for by the lime salts present. In all respects the Donyland water closely resembles many of the sand waters. Amongst this group of moder- ately soft waters we find the amount of chlorides varies very considerably ; but the wells yielding the largest quantity are sunk near the sea and close to a tidal river, the Blackwater. It will be observed that the waters in these two groups are all obtained from wells at and south of Colchester. North of that town all the deep well waters I have examined are from the chalk and contain over ten grains of carbonate of lime per gallon. They therefore fall into group III. (Table V.). The first eleven waters in this group, and five out of the last six, are derived from near the outcrop of the chalk or from places in which the London Clay and Tertiary sands are thinning out. In nearly all, the chlorides are very small in amount. The exceptions are at Mistley and Grays, both near the sea or a tidal river. In nearly all the alkalinity is due to carbonate of lime, the exceptions being the Mistley water, which contains probably about four grains of carbonate of soda per gallon, and the Stratford water (Phoenix Works), which contains about ten grains. The only other sample from Stratford (Howard's Chemical Works), on the other hand, contains little, if any carbonate of soda. Many of the Tertiary sand waters are very hard (due to both magnesia and lime), but contain very much more chlorides, sulphates, etc. (of soda chiefly), and some are so brackish as almost certainly to suggest infiltration of sea water. This is more probable, since all of them come from sources near tidal rivers or the sea. The last water on this list, that from the Beckton Gas Works, resembles some of these waters in being brackish; yet it is sunk well into the chalk, and I am told that many wells in that neighbourhood have been sunk to considerable depths into the chalk, yet have yielded waters so brackish as to be useless, and the wells have been closed. Reviewing the whole three groups, we find that most of the chalk waters in the south of the county and in the north-east resemble each other in containing considerable amounts of carbonate of lime and very little chloride and carbonate of sodium; but differ from the chalk waters in other portions of the county, where the chalk lies at a much greater depth, since the latter contain very little lime and D 2