PLEISTOCENE GEOLOGY OF THE THAMES VALLEY. 365 acidic water upon the Chalk of the district. It is evident, however, that a process which in other districts has produced, but comparatively infinitesimal results must have been favoured in this neighbourhood by conditions which have greatly accele- rated and regulated its working. Sir Joseph Prestwich in his masterly essay upon the origin of the Sand and Gravel-pipes in the Chalk (9) was the first to attack the subject of the conditions which must necessarily govern their formation. He maintained that pipes were not only the result of the chemical dissolution of the Chalk, but, moreover, under existing conditions in the great majority of instances they could not now be formed. He argued that the existence of a higher level of saturation was essential to the formation of pipes, and this increase in height was of a secondary nature, depending not so much upon the elevation of the land above the sea as upon the relative permeability of the Chalk and its superincumbent strata together with the unbroken continuity of the latter across broad stretches of country. Further he held that the pipes did not necessarily imply the existence of fissures or joints in the Chalk, but that such occurrences would retard rather than accelerate their formation. In the case before us, however, Prestwich's con- clusions cannot be applied in their totality, but rather require some little modification. It is clear that there is one important distinction between the dissolution of the Chalk into pipes on the one hand and the formation of valleys by the same means on the other. In the one case the conditions rendering the Chalk liable to the attacks of solvents are extremely local and may be but slight, but in the case of the valleys the conditions are not local, in the sense of the term applied to the pipes, but on the contrary extend over a considerable horizontal distance, giving rise to definite lines or planes of weakness. The nature of these lines of weak- ness, which constitute the valley axes, is shown by the geotec- tonic geology of the district. The Chalk of the Grays Thurrock Area occurs as an inlier brought up by a small anticlinal fold, later in date than the great Wealden and London Basin movements as is indicated by the following data. At Stifford it in common with the Lower London Tertiaries dips to the north at an angle of about 10°, and thus is soon lost beneath the London Clay. But in