THE CHIGWELL ROW MEDICINAL SPRINGS. 67 with some considerable acidity. Upon the whole, I can venture to pronounce it a useful purging Chalybeate.19 [The writer next discourses at considerable length on various properties of water and its action on different substances, but his remarks are omitted, as being of general, not specially of; local, interest. He then returns to the Chigwell Row well, of the water of which he says] it will here be necessary to say something more, before I begin with its properties and efficacy as a medicine. The earth, for some considerable distance round these places where this mineral water issues out. is of a black foetid loam, in appearance like a black rotten bog20; weh is probably occasion'd by the nature of the water, as the adjoining soil seems to be a stiff clay. On inspecting these places more narrowly, I discover'd among the mud a kind of scum reflecting changeable colours; and, upon a nearer inspection, [I] found it a kind of substance composed of sharp pointed spiculae or crystals, pointing from a centre, as is observ'd in the mundick, but so tender that. no quantity could be got sufficient for any tryal.21 It tasted strong of iron. The water at first is of a dull muddy colour and lets fall an ocrey sediment. I am told that formerly people used to come [from] many miles round to drink and also bathe in these springs and receive[d] much benefit thereby. The old inhabitants say that it is a sharp water, [and that it] cures the itch, scurvy, and other cutaneous diseases. I have given it to several, who found much relief. I gave it a young woman last sumr for a most violent scabby face and anus. She drank near a pint of it every morning. In about a week, the scabs grew dry and came off. In another week's time, they were all off. She continued well and went to her place again. She sd it purg'd her sometimes 3 or 4 times a day; and 19 Mr. Dalton writes:—"The chemical re-actions effected are:—(1) with galls, the "formation of black tannate of iron; (2) with ammonia carbonate, of green protoxide of iron; "(3) with lime-water, of the same, tinging the cloud of insoluble carbonate and sulphate of "lime; and 4) with acetate of lead, of insoluble lead carbonate and sulphate. The decom- "position of the carbonate of iron into peroxide upon continued exposure to air destroys the "blackening action of gall-tinctuie. Evaporation would leave the soluble ingredients as "crystals (see note 24)." 20 Mr. Dalton writes:—"The blackening of the soil is due to the formation of tannate "(or allied salts) of iron by the vegetable acids; partly, perhaps, also to the action of the "iron oxide on decomposing matter, producing compounds akin to humus." at Mr. Dalton writes:—"The iridescent film of peroxide of iron is exceedingly thin and "brittle. Though it is of very common occurrence, I have never observed it to exhibit any "such stellar structure as that described. The film on lime-water, mentioned further on, is. "similarly composed of insoluble carbonate on contact with air."